Characterisation of individual aerosol particles on moss surfaces: implications for source apportionment

The size, morphology and chemical composition of 8405 particles on moss surfaces (Hylocomium splendens) was investigated by scanning electron microscopy and energy-dispersive X-ray microanalysis. Two moss samples from three locations in Southern Norway (Alg?rd, Birkeland, Neslandsvatn) and two sampling years (1977 and 2005) each were selected leading to a total of 12 samples investigated. At all three locations, particle deposition decreased substantially with time. The major particle groups encountered include silicates, iron-rich silicates, metal oxides/hydroxides, iron oxides/hydroxides, carbonates, carbon-rich particles, silicate fly ashes, iron-rich silicate fly ashes, and iron oxide fly ashes. Between 1977 and 2005, the relative number abundance of the three fly ash groups decreased substantially from approximately 30-60% to 10-18% for the small particles (equivalent projected area diameter <1 microm), and from 10-35% to 2-9% for large particles with diameters ≥1 microm. This decrease of fly ash particles with time was overlooked in previous papers on atmospheric input of pollutants into ecosystems in Southern Norway. In general, the presence of fly ash particles is ignored in most source apportionment studies based on bulk chemical analysis. Consequently, the geogenic component (crustal component) derived from principal component analysis is overestimated systematically, as it has a similar chemical composition as the fly ash particles. The high abundance of fly ashes demonstrates the need to complement source apportionment based on bulk chemistry by scanning electron microscopy in order to avoid misclassification of this important anthropogenic aerosol component.     

Aromatized arborane/fernane hydrocarbons as biomarkers for cordaites

Previous palaeobotanical and palynological studies on coals from Euramerican Pennsylvanian (≡ Late Carboniferous) coal basins indicate a major change in coal-swamp floras, especially at the Westphalian–Stephanian (≈Kasimovian–Gzhelian, according to Geological Time Scale 2004) boundary. A flora dominated by arborescent lycophytes was replaced by a vegetation dominated by marattialean tree ferns in various Euramerican coal basins. Earlier combined palynological and organic geochemical studies on Westphalian/Stephanian coals and shales from the Saar-Nahe Basin (Germany) revealed that the distribution of aromatized arborane/fernane hydrocarbons in solvent extracts reflects the increasing importance of seed plants, especially cordaites (extinct group of gymnosperms), conifers and pteridosperms. However, the biological source of the precursor molecules could not be specified. To clarify if the arborane/fernane derivatives MATH, MAPH, DAPH 1, and DAPH 2 in Westphalian/Stephanian coals can be assigned to one of the three potential source plant groups, we analyzed coals, sediments and fossil plant remains from different Euramerican locations with respect to their biomarker composition and stable carbon isotopic composition. Thereby, stable carbon isotopic ratios showed only insignificant variations between Westphalian and Stephanian samples and proved to be an unsuitable tool to describe floral changes during the Westphalian/Stephanian of the Saar-Nahe Basin. In contrast, we were able to show for the first time that MATH, MAPH, DAPH 1 and DAPH 2 are prominent constituents only in extracts of cordaitean macrofossils and can therefore be regarded as biomarkers for this group of gymnosperms.     

Ammonia triggers the promotion of oxidative stress in the aquatic macrophyte Myriophyllum mattogrossense

The effect of increased ammonia content on sub-acute biochemical responses was assessed in the rooted submersed aquatic macrophyte Myriophyllum mattogrossense (common name: "Brazil Milfoil" or "Matogrosso Milfoil"), in a seven day aquarium experiment. The pH and temperature were monitored in order to determine the proportions of both ionized (NH4+) and un-ionized (NH3) forms of ammonia. Specific activities of several enzymes such as catalase (CAT), guaiacol peroxidase (POD), glutathione peroxidase (GPx) and glutathione S-transferase (GST's) were measured as well as the content of the soluble antioxidant glutathione and lipid peroxidation were determined as these parameters are considered as indicators of cell-level disorder. The results showed that ammonia is able to generate oxidative stress, expressed through an elevated GSH content and the enhancement of CAT, POD, GPx and GST's activities in treatments with elevated ammonia content. As the toxic mechanism of ammonia is a complex phenomenon, this work adds an additional point of view to explain in parts the oxidative stress generating effect of ammonia promoting oxidative stress. Additionally the different modes of action proposed by other research groups are discussed, thus trying to combine the various points of view.     

Chemical characteristics of size-resolved aerosols in winter in Beijing

Size-resolved aerosols were continuously collected by a Nano Sampler for 13 days at an urban site in Beijing during winter 2012 to measure the chemical composition of ambient aerosol particles. Data collected by the Nano Sampler and an ACSM(Aerodyne Aerosol Chemical Speciation Monitor) were compared. Between the data sets,similar trends and strong correlations were observed,demonstrating the validity of the Nano Sampler. PM10 and PM2.5concentrations during the measurement were 150.5 ± 96.0 μg/m3(mean ± standard variation)and 106.9 ± 71.6 μg/m3,respectively. The PM2.5/PM10 ratio was 0.70 ± 0.10,indicating that PM2.5dominated PM10. The aerosol size distributions showed that three size bins of 0.5–1,1–2.5 and 2.5–10 μm contributed 21.8%,23.3% and 26.0% to the total mass concentration(TMC),respectively. OM(organic matter) and SIA(secondary ionic aerosol,mainly SO42-,NO3-and NH4+) were major components of PM2.5. Secondary compounds(SIA and secondary organic carbon) accounted for half of TMC(about 49.8%) in PM2.5,and suggested that secondary aerosols significantly contributed to the serious particulate matter pollution observed in winter. Coal burning,biomass combustion,vehicle emissions and SIA were found to be the main sources of PM2.5. Mass concentrations of water-soluble ions and undetected materials,as well as their fractions in TMC,strikingly increased with deteriorating particle pollution conditions,while OM and EC(elemental carbon) exhibited different variations,with mass concentrations slightly increasing but fractions in TMC decreasing.     

Derivation of soil values for the path ‘Soil-Soil Organisms’ for metals and selected organic compounds using species sensitivity distributions

BACKGROUND, AIMS AND SCOPE: According to the German Federal Soil Protection Act, the natural function of soil as a habitat for human beings, animals, plants and soil organisms is, among other things, to be protected by deriving soil values for important chemicals regarding their amounts in the environment, their persistence and/or their toxicity. This contribution presents the results of the mathematical derivation of such values for nine metals and ten organic substances from soil ecotoxicological effect values available in the literature for microbial processes, plants and soil invertebrates. MATERIAL AND METHODS: Ecotoxicological data were mostly extracted from published papers and reports and had to originate from valid studies that were performed according to internationally standardised guidelines (e.g. ISO) or were otherwise well documented, plausible and performed according to accepted laboratory practice. As test results, both structural (i.e., effects on mortality, growth or reproduction) and functional (i.e., effects on microbial activity or organic matter breakdown) parameters were included. The derivation of soil values was performed using the distribution based extrapolation model (DIBAEX) and EC(50)s (Effective Concentration) as input data. RESULTS: For 19 compounds, soil values could be calculated. In 18 of these 19 cases clear laboratory ecotoxicological effects (i.e., EC50 values) below the calculated soil value have been found in the literature. DISCUSSION: In those few cases where a comparison with field studies is possible, effects have been observed in the same order of magnitude as the calculated soil values. A comparison with other similar approaches confirmed the plausibility of the calculated values. CONCLUSIONS: The DIBAEX-method is a feasible and widely accepted method for deriving soil values from ecotoxicological input data. Data availability was already satisfactory for some substances, but other substances, especially organics, were only poorly covered. The soil values presented here were based on EC50 input data. However, depending on the protection level aimed at by using soil values in legislation, it might be appropriate to use other input data such as NOECs in the derivation process. RECOMMENDATIONS AND PERSPECTIVES: It is recommended to generate an appropriate number of data for further relevant substances by means of a test battery or multi-species approaches such as terrestrial model ecosystems. These tests should also consider the influence of the bioavailability of substances. A final recommendation for legally binding soil values demands a plausibility check of the mathematically derived values. This should include a comparison with natural background concentrations, soil values for other pathways and soil values used in legislation of other countries. Finally, expert judgement always has to be considered.     

Rethinking Tropical Forest Conservation: Perils in Parks

Abstract: According to some conservationists, large, pristine, uninhabited parks are the defining criterion of success in conserving tropical forests. They argue that human residents in tropical forests inevitably deplete populations of large animals through hunting, which triggers a chain reaction of ecological events that greatly diminish the conservation value of these forests. Hence, they believe that removal of people from tropical forests is an essential step in the creation of successful parks and in the conservation of nature in the tropics. This approach can lead to undesirable consequences, however. Forest residents—and rural people generally—are potent political actors in tropical forest regions and an essential component of the environmental political constituencies that are necessary for the long-term conservation of tropical forests. In Amazonia and elsewhere, rural people are defending far bigger areas of tropical forest from unfettered deforestation and logging than are parks, thereby conserving the ecological services provided by these forests and the majority of their component plant and animal species. Moreover, the data are too sparse to judge the effects of forest peoples on populations of large forest animals. The establishment of pristine, tropical forest parks is an important conservation goal, but the exclusive pursuit of this goal undermines the broader objectives of conservation when it identifies forest residents and other rural people as the enemies of nature.     

Ethnosciences––A step towards the integration of scientific and indigenous forms of knowledge in the management of natural resources for the future

Integration of indigenous knowledge and ethnoscientific approaches into contemporary frameworks for conservation and sustainable management of natural resources will become increasingly important in policies on an international and national level, both in countries that are industrialised and those that have a developing status. We set the scene on how this can be done by exploring the key conditions and dimensions of a dialogue between ȁ8ontologiesȁ9 and the roles, which ethnosciences could play in this process. First, the roles of ethnosciences in the context of sustainable development were analysed, placing emphasis on the implications arising when western sciences aspire to relate to indigenous forms of␣knowledge. Secondly, the contributions of ethnosciences to such an ȁ8inter- ontological dialogueȁ9 were explored, based on an ethnoecological study of the encounter of sciences and indigenous knowledge in the Andes of Bolivia, and reviewed experiences from mangrove systems in Kenya, India and Sri Lanka, and from case-studies in other ecosystems world-wide, incl. Australia, Burkina Faso, Ecuador, Ethiopia, Guatemala, Indonesia, Nepal, Niger, Philippines, Senegal, South-Africa and Tanzania.     

Use of retired oil and gas platforms for fisheries in the Gulf of Mexico

Petroleum resources are declining on the continental shelf and will, eventually, result in the loss of ~?30,000 jobs in related industries. Retired oil and gas platforms could be redeployed to culture fish and employ citizens in coastal areas. The Energy Policy Act 2005 Section 388 of Public Law [PL] 109-58 30 CFR 285.1000 Subpart J encourages the use of the retired structures for alternate uses. At present, there are no fishermen currently taking advantage of this legislation. We suggest amending existing laws to improve the likelihood that retired platforms are used to culture fish and invertebrates. In the future, the abandoned oil and gas infrastructure could also be used to recover stranded petroleum and reserves located in deeper horizons.     

Thermal reaction norms for growth vary among cohorts of Pacific cod (Gadus macrocephalus)

While much effort has been directed at determining the spatial scales of adaptation in thermal reaction norms for growth, it is widely assumed that these reaction norms have high temporal stability. Water temperatures in the Gulf of Alaska in 2007 were the coldest on record since the mid-1970s and we present evidence that the thermal reaction norm for growth of age-0 Pacific cod (Gadus macrocephalus) in this cohort differed significantly from two adjacent cohorts. In addition to exhibiting higher growth potential at low temperatures, the 2007 cohort had a higher mean vertebral count, consistent with the widespread thermal effect known as “Jordan’s Rule.” Variation among cohorts in these physiological and morphological traits suggests a persistent response to environmental history (epigenetic effect). Temperature-induced phenotypic plasticity in the reaction norm for growth has significant implications for using growth rates to evaluate habitat quality and illustrates the complex responses of fishes to climate variability.